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Enantioselective Claisen Rearrangements with a Hydrogen-Bond Donor Catalyst

[Image: see text] N,N′-Diphenylguanidinium ion associated with the non-coorinating BArF counterion is shown to be an effective catalyst for the [3,3]-sigmatropic rearrangement of a variety of substituted allyl vinyl ethers. Highly enantioselective catalytic Claisen rearrangements of ester-substitute...

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Detalhes bibliográficos
Main Authors: Uyeda, Christopher, Jacobsen, Eric N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2547484/
https://ncbi.nlm.nih.gov/pubmed/18576616
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803370x
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