Isolation and Study of Ruthenium–Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru(V)–Oxo with Significant Oxyl Radical Character

High-valent Ru(V)–oxo intermediates have long been proposed in catalytic oxidation chemistry, but investigations into their electronic and chemical properties have been limited due to their reactive nature and rarity. The incorporation of Ru into the [Co(3)O(4)] subcluster via the singlestep assembl...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Amtawong, Jaruwan, Balcells, David, Wilcoxen, Jarett, Handford, Rex C., Biggins, Naomi, Nguyen, Andy I., Britt, R. David, Tilley, T. Don
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2019
Ämnen:
Article
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187899/
https://ncbi.nlm.nih.gov/pubmed/31697896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10320
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