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Isolation and Study of Ruthenium–Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru(V)–Oxo with Significant Oxyl Radical Character
High-valent Ru(V)–oxo intermediates have long been proposed in catalytic oxidation chemistry, but investigations into their electronic and chemical properties have been limited due to their reactive nature and rarity. The incorporation of Ru into the [Co(3)O(4)] subcluster via the singlestep assembl...
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| Veröffentlicht in: | J Am Chem Soc |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7187899/ https://ncbi.nlm.nih.gov/pubmed/31697896 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10320 |
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