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Isolation and Study of Ruthenium–Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru(V)–Oxo with Significant Oxyl Radical Character

High-valent Ru(V)–oxo intermediates have long been proposed in catalytic oxidation chemistry, but investigations into their electronic and chemical properties have been limited due to their reactive nature and rarity. The incorporation of Ru into the [Co(3)O(4)] subcluster via the singlestep assembl...

詳細記述

保存先:
書誌詳細
出版年:J Am Chem Soc
主要な著者: Amtawong, Jaruwan, Balcells, David, Wilcoxen, Jarett, Handford, Rex C., Biggins, Naomi, Nguyen, Andy I., Britt, R. David, Tilley, T. Don
フォーマット: Artigo
言語:Inglês
出版事項: 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187899/
https://ncbi.nlm.nih.gov/pubmed/31697896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10320
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