Isolation and Study of Ruthenium–Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru(V)–Oxo with Significant Oxyl Radical Character

High-valent Ru(V)–oxo intermediates have long been proposed in catalytic oxidation chemistry, but investigations into their electronic and chemical properties have been limited due to their reactive nature and rarity. The incorporation of Ru into the [Co(3)O(4)] subcluster via the singlestep assembl...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Amtawong, Jaruwan, Balcells, David, Wilcoxen, Jarett, Handford, Rex C., Biggins, Naomi, Nguyen, Andy I., Britt, R. David, Tilley, T. Don
Format: Artigo
Language:Inglês
Published: 2019
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7187899/
https://ncbi.nlm.nih.gov/pubmed/31697896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10320
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