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Photocatalytic Aerobic Oxidation by a bis-Porphyrin-Ruthenium(IV) μ-Oxo Dimer: Observation of a Putative Porphyrin-Ruthenium(V)-Oxo Intermediate
[Image: see text] The title complexes catalyze the aerobic oxidations of hydrocarbons using visible light and atmospheric oxygen as oxygen source in sequences employing photo-disproportionation reactions. The putative oxidants, ruthenium(V)-oxo porphyrin species, can be detected and studied in real...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2877504/ https://ncbi.nlm.nih.gov/pubmed/20394434 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1005938 |
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