Photocatalytic Aerobic Oxidation by a bis-Porphyrin-Ruthenium(IV) μ-Oxo Dimer: Observation of a Putative Porphyrin-Ruthenium(V)-Oxo Intermediate

[Image: see text] The title complexes catalyze the aerobic oxidations of hydrocarbons using visible light and atmospheric oxygen as oxygen source in sequences employing photo-disproportionation reactions. The putative oxidants, ruthenium(V)-oxo porphyrin species, can be detected and studied in real...

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Bibliographic Details
Main Authors: Vanover, Eric, Huang, Yan, Xu, Libin, Newcomb, Martin, Zhang, Rui
Format: Artigo
Language:Inglês
Published: 2010
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2877504/
https://ncbi.nlm.nih.gov/pubmed/20394434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol1005938
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