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A catalytic di-heme bis-Fe(IV) intermediate, alternative to an Fe(IV)=O porphyrin radical

High-valent iron species are powerful oxidizing agents in chemical and biological catalysis. The best characterized form of an Fe(V) equivalent described in biological systems is the combination of a b-type heme with Fe(IV)=O and a porphyrin or amino acid cation radical (termed Compound I). This wor...

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Bibliografiske detaljer
Main Authors: Li, Xianghui, Fu, Rong, Lee, Sheeyong, Krebs, Carsten, Davidson, Victor L., Liu, Aimin
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2008
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2438432/
https://ncbi.nlm.nih.gov/pubmed/18562294
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0801643105
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