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Photochemical generation and kinetic studies of a putative porphyrin-ruthenium(V)-oxo species

Photo-disproportionation of a bis-porphyrin-diruthenium(IV) μ-oxo dimer gave a porphyrin-ruthenium(III) species and a putative poprhyrin-ruthenium(V)-oxo species that can be detected and studied in real time via laser flash photolysis methods. As determined by its spectral and kinetic behavior, the...

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Main Authors: Zhang, Rui, Vanover, Eric, Luo, Weilong, Newcomb, Martin
Formato: Artigo
Idioma:Inglês
Publicado: 2014
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4071932/
https://ncbi.nlm.nih.gov/pubmed/24770388
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4dt00649f
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