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Photochemical Production of a Highly Reactive Porphyrin-Iron-Oxo Species
Oxidation of 5,10,15,20-tetramesitylporphyrin-iron(III) perchlorate, (TMP)Fe(III)(ClO(4)), with ferric perchlorate in acetonitrile gave a metastable species identified as (TMP)Fe(IV)(ClO(4))(2) that decayed within seconds to the known isomeric species (TMP(+•))Fe(III)(ClO(4))(2). Irradiation of the...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2525790/ https://ncbi.nlm.nih.gov/pubmed/17284026 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic061972w |
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