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Formation of Stable and Metastable Porphyrin- and Corrole-Iron(IV) Complexes and Isomerizations to Iron(III) Macrocycle Radical Cations
Oxidations of three porphyrin-iron(III) complexes (1) with ferric perchlorate, Fe(ClO(4))(3), in acetonitrile solutions at −40 °C gave metastable porphyrin-iron(IV) diperchlorate complexes (2) that isomerized to known iron(III) diperchlorate porphyrin radical cations (3) when the solutions were warm...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2008
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2680251/ https://ncbi.nlm.nih.gov/pubmed/19013647 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2008.09.017 |
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