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Tunneling in C-H Oxidation Reactions by an Oxoiron(IV) Porphyrin Radical Cation: Direct Measurements of Very Large H/D Kinetic Isotope Effects
[Image: see text] Rate constants for oxidations of benzyl alcohol-d(0) and -d(7) by oxoiron(IV) tetramesitylporphyrin radical cation perchlorate in acetonitrile were measured in single-turnover kinetic studies. The kinetic isotope effect (k(H)/k(D)) increased from 28 at 23 °C to 360 at −30 °C due to...
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| Główni autorzy: | , , |
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| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
2008
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2642477/ https://ncbi.nlm.nih.gov/pubmed/18512909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802484n |
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