A carregar...
Tunneling in C-H Oxidation Reactions by an Oxoiron(IV) Porphyrin Radical Cation: Direct Measurements of Very Large H/D Kinetic Isotope Effects
[Image: see text] Rate constants for oxidations of benzyl alcohol-d(0) and -d(7) by oxoiron(IV) tetramesitylporphyrin radical cation perchlorate in acetonitrile were measured in single-turnover kinetic studies. The kinetic isotope effect (k(H)/k(D)) increased from 28 at 23 °C to 360 at −30 °C due to...
Na minha lista:
| Main Authors: | , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2642477/ https://ncbi.nlm.nih.gov/pubmed/18512909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802484n |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|