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M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt(III)‐Oxyl and Cobalt(III)‐Oxo Complexes
Terminal oxo complexes of late transition metals are frequently proposed reactive intermediates. However, they are scarcely known beyond Group 8. Using mass spectrometry, we prepared and characterized two such complexes: [(N4Py)Co(III)(O)](+) (1) and [(N4Py)Co(IV)(O)](2+) (2). Infrared photodissocia...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autoři: | , , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
John Wiley and Sons Inc.
2019
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6618258/ https://ncbi.nlm.nih.gov/pubmed/31083766 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904546 |
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