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Characterized cis-Fe(V)(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
Fe(V)(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, the inability to accumulate these intermediates in solution has thus far prevented thei...
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| Publié dans: | Nat Commun |
|---|---|
| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Nature Publishing Group UK
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6385299/ https://ncbi.nlm.nih.gov/pubmed/30796210 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-08668-2 |
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