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Characterized cis-Fe(V)(O)(OH) intermediate mimics enzymatic oxidations in the gas phase

Fe(V)(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, the inability to accumulate these intermediates in solution has thus far prevented thei...

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Détails bibliographiques
Publié dans:Nat Commun
Auteurs principaux: Borrell, Margarida, Andris, Erik, Navrátil, Rafael, Roithová, Jana, Costas, Miquel
Format: Artigo
Langue:Inglês
Publié: Nature Publishing Group UK 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6385299/
https://ncbi.nlm.nih.gov/pubmed/30796210
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-08668-2
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