Closed Shell Iron(IV) Oxo Complex with an Fe–O Triple Bond: Computational Design, Synthesis, and Reactivity

Iron(IV)‐oxo intermediates in nature contain two unpaired electrons in the Fe–O antibonding orbitals, which are thought to contribute to their high reactivity. To challenge this hypothesis, we designed and synthesized closed‐shell singlet iron(IV) oxo complex [(quinisox)Fe(O)](+) (1(+); quinisox‐H=(...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Andris, Erik, Segers, Koen, Mehara, Jaya, Rulíšek, Lubomír, Roithová, Jana
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Research Articles
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756500/
https://ncbi.nlm.nih.gov/pubmed/32926539
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009347
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