Closed Shell Iron(IV) Oxo Complex with an Fe–O Triple Bond: Computational Design, Synthesis, and Reactivity

Iron(IV)‐oxo intermediates in nature contain two unpaired electrons in the Fe–O antibonding orbitals, which are thought to contribute to their high reactivity. To challenge this hypothesis, we designed and synthesized closed‐shell singlet iron(IV) oxo complex [(quinisox)Fe(O)](+) (1(+); quinisox‐H=(...

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Andris, Erik, Segers, Koen, Mehara, Jaya, Rulíšek, Lubomír, Roithová, Jana
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Research Articles
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756500/
https://ncbi.nlm.nih.gov/pubmed/32926539
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009347
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