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A concise, enantioselective approach for the synthesis of yohimbine alkaloids
We report a concise, enantioselective synthesis of the yohimbine alkaloids (−)-rauwolscine and (−)-alloyohimbane. The key transformation involves a highly enantio- and diastereoselective NHC-catalyzed dimerization and an amidation/N-acyliminium ion cyclization sequence to furnish four of the five re...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
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| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2020
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7185878/ https://ncbi.nlm.nih.gov/pubmed/31951394 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b12319 |
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