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Concise enantioselective synthesis of diospongins A and B

Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activa...

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Bibliographic Details
Main Authors: Stefan, Eric, Nalin, Ansel P., Taylor, Richard E.
Format: Artigo
Language:Inglês
Published: 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3775279/
https://ncbi.nlm.nih.gov/pubmed/24058215
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.05.081
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