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Dictating Thermodynamic Control through Tethering: Applications to Stereoselective Bis-Spiroketal Synthesis
Approaches to stereocontrol that invoke thermodynamic control fail when two or more potential products are energetically similar, but rational structural perturbations can be employed to break the energetic degeneracy and provide selective transformations. This manuscript illustrates that tethering...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2020
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7141965/ https://ncbi.nlm.nih.gov/pubmed/31991022 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201916270 |
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