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Stereoselective Synthesis of Benzannulated Spiroketals: Influence of the Aromatic Ring on Reactivity and Conformation

[Image: see text] A systematic stereocontrolled synthesis of benzannulated spiroketals has been developed, using kinetic spirocyclization reactions of glycal epoxides, leading to a new AcOH-induced cyclization and valuable insights into the reactivity and conformations of these systems. One stereoch...

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Autors principals: Liu, Guodong, Wurst, Jacqueline M., Tan, Derek S.
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2760470/
https://ncbi.nlm.nih.gov/pubmed/19634891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901437f
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