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Iridium‐Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis
Described herein are two different methods for the synthesis of vinyl halides by a shuttle catalysis based iridium‐catalyzed transfer hydrohalogenation of unactivated alkynes. The use of 4‐chlorobutan‐2‐one or tert‐butyl halide as donors of hydrogen halides allows this transformation in the absence...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7028031/ https://ncbi.nlm.nih.gov/pubmed/31769578 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912803 |
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