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Iridium‐Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis

Described herein are two different methods for the synthesis of vinyl halides by a shuttle catalysis based iridium‐catalyzed transfer hydrohalogenation of unactivated alkynes. The use of 4‐chlorobutan‐2‐one or tert‐butyl halide as donors of hydrogen halides allows this transformation in the absence...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Yu, Peng, Bismuto, Alessandro, Morandi, Bill
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2020
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7028031/
https://ncbi.nlm.nih.gov/pubmed/31769578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912803
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