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Catalytic Asymmetric C–H Arylation of (η(6)-Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines
[Image: see text] A catalytic asymmetric direct C–H arylation of (η(6)-arene)chromium complexes to obtain planar-chiral compounds is reported. The use of the hemilabile ligand H(8)-BINAP(O) is key to providing high enantioselectivity in this transformation. We show that this methodology opens the do...
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| Publicado no: | ACS Catal |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2019
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7011738/ https://ncbi.nlm.nih.gov/pubmed/32064145 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b00918 |
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