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Tricarbonyl(η6-Arene)Chromium(0) Complexes as Chiral Auxiliaries: Asymmetric Synthesis of β-Lactones

The optically pure tricarbonyl(η(6)-2-substituted benzaldehydes)chromium are used as chiral auxiliaries in the condensation with a series of doubly lithiated carboxylic acids. The intramolecular ring closure of the obtained Cr(CO)(3) complexed β-hydroxyacids affords the optically pure β-lactones in...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Buttero, Paola Del, Montrasio, Deborah
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2001
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6236448/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/60100013
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