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Tricarbonyl(η6-Arene)Chromium(0) Complexes as Chiral Auxiliaries: Asymmetric Synthesis of β-Lactones
The optically pure tricarbonyl(η(6)-2-substituted benzaldehydes)chromium are used as chiral auxiliaries in the condensation with a series of doubly lithiated carboxylic acids. The intramolecular ring closure of the obtained Cr(CO)(3) complexed β-hydroxyacids affords the optically pure β-lactones in...
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| Publié dans: | Molecules |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
MDPI
2001
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6236448/ https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/60100013 |
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