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Single-Step Enantioselective Synthesis of Mechanically Planar Chiral [2]Rotaxanes Using a Chiral Leaving Group Strategy

[Image: see text] We report a one-step enantioselective synthesis of mechanically planar chiral [2]rotaxanes. Previous studies of such molecules have generally involved the separation of enantiomers from racemic mixtures or the preparation and separation of diastereomeric intermediates followed by p...

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Pubblicato in:J Am Chem Soc
Autori principali: Tian, Chong, Fielden, Stephen D. P., Pérez-Saavedra, Borja, Vitorica-Yrezabal, Iñigo J., Leigh, David A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2020
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7266371/
https://ncbi.nlm.nih.gov/pubmed/32356978
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03447
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