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Enantioselective [4+2] Annulation to the Concise Synthesis of Chiral Dihydrocarbazoles

A highly efficient phosphine-catalyzed enantioselective [4 + 2] annulation of allenoates with 3-nitroindoles or 3-nitrobenzothiophenes has been developed. The protocol represents a unique dearomatization–aromatization process to access functionalized dihydrocarbazoles or dihydrodibenzothiophenes wit...

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Detalhes bibliográficos
Publicado no:iScience
Main Authors: Wang, Haiyang, Hu, Qingdong, Wang, Mingxu, Guo, Chang
Formato: Artigo
Idioma:Inglês
Publicado em: Elsevier 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6995259/
https://ncbi.nlm.nih.gov/pubmed/32004992
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2020.100840
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