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Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
When Boc-L-Val-OH was used as a ligand for the enantioselective Pd(II)-catalyzed annulation of N,N-substituted aminomethyl ferrocene derivatives with diarylethynes, ferrocenes with planar chirality could be achieved with excellent enantioselectivity (up to 99% ee).
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3778326/ https://ncbi.nlm.nih.gov/pubmed/24062858 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.222 |
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