Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes

When Boc-L-Val-OH was used as a ligand for the enantioselective Pd(II)-catalyzed annulation of N,N-substituted aminomethyl ferrocene derivatives with diarylethynes, ferrocenes with planar chirality could be achieved with excellent enantioselectivity (up to 99% ee).

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Detalles Bibliográficos
Autores principales: Shi, Yan-Chao, Yang, Rong-Fei, Gao, De-Wei, You, Shu-Li
Formato: Artigo
Lenguaje:Inglês
Publicado: Beilstein-Institut 2013
Materias:
Letter
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3778326/
https://ncbi.nlm.nih.gov/pubmed/24062858
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.222
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