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Stretchable chiral pockets for palladium-catalyzed highly chemo- and enantioselective allenylation

Pyrazolones are a vital class of heterocycles possessing various biological properties and much attention is paid to the diversified synthesis of enantiopure pyrazolone derivatives. We describe here the development of diphenylphosphinoalkanoic acid based chiral bisphosphine ligands, which are succes...

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Publicat a:Nat Commun
Autors principals: Zhang, Yuchen, Zhang, Xue, Ma, Shengming
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8065118/
https://ncbi.nlm.nih.gov/pubmed/33893276
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-22498-1
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