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Stretchable chiral pockets for palladium-catalyzed highly chemo- and enantioselective allenylation

Pyrazolones are a vital class of heterocycles possessing various biological properties and much attention is paid to the diversified synthesis of enantiopure pyrazolone derivatives. We describe here the development of diphenylphosphinoalkanoic acid based chiral bisphosphine ligands, which are succes...

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Pubblicato in:Nat Commun
Autori principali: Zhang, Yuchen, Zhang, Xue, Ma, Shengming
Natura: Artigo
Lingua:Inglês
Pubblicazione: Nature Publishing Group UK 2021
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8065118/
https://ncbi.nlm.nih.gov/pubmed/33893276
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-22498-1
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