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Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins

An efficient method for intermolecular branch-selective allylic C-H amidation has been accomplished via Ir(III) catalysis. The reaction proceeds through initial allylic C-H activation, supported by the isolation and crystallographic characterization of an allyl-Ir(III) intermediate, followed by a su...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lei, Honghui, Rovis, Tomislav
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6986200/
https://ncbi.nlm.nih.gov/pubmed/30715868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00237
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