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Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes

We report a three-component diamination of simple unactivated alkenes using an electrophilic nitrene source and amine nucleophiles. The reaction provides rapid access to 1,2-vicinal diamines from terminal alkenes through a one-pot protocol. The transformation proceeds smoothly with excellent toleran...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Synthesis (Stuttg)
Prif Awduron: Lee, Sumin, Jang, Young Jin, Phipps, Erik J. T., Lei, Honghui, Rovis, Tomislav
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2020
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8290961/
https://ncbi.nlm.nih.gov/pubmed/34290458
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0039-1690756
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