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Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes
An intramolecular Ir(III)-catalyzed regiodivergent oxyamination of unactivated alkenes provides valuable γ-lactams, γ-lactones and δ-lactams. The regioselectivity is controlled by the electronically tunable cyclopentadienyl Ir(III)-complexes enabling oxyamination via either 5-exo or 6-endo pathways....
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6980349/ https://ncbi.nlm.nih.gov/pubmed/31310537 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06366 |
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