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Rh(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation
We have developed a Rh(III)-catalyzed cyclopropanation of unactivated olefins initiated by an alkenyl C–H activation. A variety of 1,1-disubstituted olefins undergo efficient cyclopropanation with a slight excess of alkene stoichiometry. A series of mechanistic interrogations implicate a metal-carbe...
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| Publicado no: | Synlett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7428168/ https://ncbi.nlm.nih.gov/pubmed/32801480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0039-1690130 |
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