Stereoselective Csp(3)−Csp(2) Cross‐Couplings of Chiral Secondary Alkylzinc Reagents with Alkenyl and Aryl Halides

We report palladium‐catalyzed cross‐coupling reactions of chiral secondary non‐stabilized dialkylzinc reagents, prepared from readily available chiral secondary alkyl iodides, with alkenyl and aryl halides. This method provides α‐chiral alkenes and arenes with very high retention of configuration (d...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Skotnitzki, Juri, Kremsmair, Alexander, Keefer, Daniel, Gong, Ye, de Vivie‐Riedle, Regina, Knochel, Paul
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2019
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6973128/
https://ncbi.nlm.nih.gov/pubmed/31529574
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201910397
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