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Highly Selective Reactions of Unbiased Alkenyl Halides and Alkylzinc Halides: Negishi-Plus Couplings

[Image: see text] High yelding stereo- and chemo-selective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive.

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Autori principali: Krasovskiy, Arkady, Lipshutz, Bruce H.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3365517/
https://ncbi.nlm.nih.gov/pubmed/21739947
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201307y
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