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Functionalization of remote C(sp(3))-H bonds enabled by copper-catalyzed coupling of O-acyloximes with terminal alkynes
Transition metal catalyzed Sonogashira cross-coupling of terminal alkynes with aryl(vinyl) (pseudo)halides has been successfully extended to alkyl halides for the synthesis of functionalized internal alkynes. The direct alkynylation of remote unfunctionalized sp(3) carbon by terminal alkynes remains...
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| Publicado no: | Nat Commun |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group UK
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6972843/ https://ncbi.nlm.nih.gov/pubmed/31964870 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-14292-2 |
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