Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp(3))−H bonds with alkynes

Transition metal-catalyzed enantioselective Sonogashira-type oxidative C(sp(3))—C(sp) coupling of unactivated C(sp(3))−H bonds with terminal alkynes has remained a prominent challenge. The difficulties mainly stem from the regiocontrol in unactivated C(sp(3))—H bond functionalization and the inhibit...

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Publicado no:Nat Commun
Main Authors: Zhang, Zhen-Hua, Dong, Xiao-Yang, Du, Xuan-Yi, Gu, Qiang-Shuai, Li, Zhong-Liang, Liu, Xin-Yuan
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6908613/
https://ncbi.nlm.nih.gov/pubmed/31831750
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-13705-1
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