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C-H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp(3) C-H Bonds Catalyzed by Platinum Tetraiodide

We report a catalytic intramolecular coupling between terminal unactivated alkynes and sp(3) C-H bonds via the through-space hydride transfer (HT-cyclization of alkynes). This method enables one-step preparation of complex heterocyclic compounds by α-alkenylation of readily available cyclic ethers a...

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Bibliografiske detaljer
Main Authors: Vadola, Paul A., Sames, Dalibor
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2971677/
https://ncbi.nlm.nih.gov/pubmed/19852462
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906480w
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