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C-H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp(3) C-H Bonds Catalyzed by Platinum Tetraiodide
We report a catalytic intramolecular coupling between terminal unactivated alkynes and sp(3) C-H bonds via the through-space hydride transfer (HT-cyclization of alkynes). This method enables one-step preparation of complex heterocyclic compounds by α-alkenylation of readily available cyclic ethers a...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2971677/ https://ncbi.nlm.nih.gov/pubmed/19852462 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906480w |
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