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Development of an Imine Chaperone for Selective C-H Functionalization of Alcohols via Radical Relay
The design of a radical relay chaperone to promote selective C-H functionalizations is described. A saccharine-based imine was found to be uniquely suited to effect C-H amination of alcohols via an in situ generated hemiaminal. This radical chaperone facilitates the mild generation of an N-centered...
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| Publicat a: | J Org Chem |
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| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6948922/ https://ncbi.nlm.nih.gov/pubmed/31513401 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02052 |
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