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Oxodealkenylative cleavage of alkene C(sp(3))–C(sp(2)) bonds: A practical method for introducing carbonyls into chiral pool materials
Herein we report a one-pot protocol for the oxodealkenylative introduction of carbonyl functionalities into terpenes and terpene-derived compounds. This transformation proceeds via Criegee ozonolysis of an alkene, reductive cleavage of the resulting α-alkoxy hydroperoxide, trapping of the generated...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6942233/ https://ncbi.nlm.nih.gov/pubmed/31692203 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201913201 |
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