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Catalytic asymmetric allylation of aldehydes with alkenes through allylic C(sp(3))–H functionalization mediated by organophotoredox and chiral chromium hybrid catalysis
We describe a hybrid system that realizes cooperativity between an organophotoredox acridinium catalyst and a chiral chromium complex catalyst, thereby enabling unprecedented exploitation of unactivated hydrocarbon alkenes as precursors to chiral allylchromium nucleophiles for asymmetric allylation...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6430092/ https://ncbi.nlm.nih.gov/pubmed/30996935 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05677c |
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