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Lewis Acid Catalyzed Enantioselective Photochemical Rearrangements on the Singlet Potential Energy Surface
[Image: see text] The oxadi-π-methane rearrangement of 2,4-cyclohexadienones to bicyclic ketones was found to proceed with high enantioselectivity (92–97% ee) in the presence of catalytic amounts of a chiral Lewis acid (15 examples, 52–80% yield). A notable feature of the transformation is the fact...
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| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical Society
2019
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6935867/ https://ncbi.nlm.nih.gov/pubmed/31814393 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b12068 |
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