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Enantioselective photochemistry via Lewis acid catalyzed triplet energy transfer

Relatively few catalytic systems are able to control the stereochemistry of electronically excited organic intermediates. Here we report the discovery that a chiral Lewis acid complex can catalyze triplet energy transfer from an electronically excited photosensitizer. This strategy is applied to asy...

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Detalhes bibliográficos
Publicado no:Science
Main Authors: Blum, Travis R., Miller, Zachary D., Bates, Desiree M., Guzei, Ilia A., Yoon, Tehshik P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5501084/
https://ncbi.nlm.nih.gov/pubmed/27980203
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aai8228
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