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Enantioselective Lewis Acid Catalyzed ortho Photocycloaddition of Olefins to Phenanthrene‐9‐carboxaldehydes
Visible‐light irradiation (λ=457 nm) enabled the enantioselective ortho photocycloaddition of olefins to phenanthrene‐9‐carboxaldehydes (15 examples, 46–93 % yield, 82–98 % ee). A chiral oxazaborolidine Lewis acid (20 mol %) was employed as the catalyst. It operates by coordination to the aldehyde i...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
|---|---|
| Hoofdauteurs: | , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2018
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6220838/ https://ncbi.nlm.nih.gov/pubmed/30225921 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808919 |
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