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Solid‐State and Gas‐Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates

An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver nitrate. Both compounds were identified by spectroscopy and the structures determined for in situ grown crystals by X‐...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Reichel, Marco, Krumm, Burkhard, Vishnevskiy, Yury V., Blomeyer, Sebastian, Schwabedissen, Jan, Stammler, Hans‐Georg, Karaghiosoff, Konstantin, Mitzel, Norbert W.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6916544/
https://ncbi.nlm.nih.gov/pubmed/31573130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201911300
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