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Solid‐State and Gas‐Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates

An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver nitrate. Both compounds were identified by spectroscopy and the structures determined for in situ grown crystals by X‐...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Reichel, Marco, Krumm, Burkhard, Vishnevskiy, Yury V., Blomeyer, Sebastian, Schwabedissen, Jan, Stammler, Hans‐Georg, Karaghiosoff, Konstantin, Mitzel, Norbert W.
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6916544/
https://ncbi.nlm.nih.gov/pubmed/31573130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201911300
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