The Nature of Chalcogen‐Bonding‐Type Tellurium–Nitrogen Interactions: A First Experimental Structure from the Gas Phase

(C(6)F(5))Te(CH(2))(3)NMe(2) (1), a perfluorophenyltellurium derivative capable of forming intramolecular N⋅⋅⋅Te interactions, was prepared and characterized. The donor‐free reference substance (C(6)F(5))TeMe (2) and the unsupported adduct (C(6)F(5))(Me)Te⋅NMe(2)Et (2 b) were studied in parallel. Mo...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Glodde, Timo, Vishnevskiy, Yury V., Zimmermann, Lars, Stammler, Hans‐Georg, Neumann, Beate, Mitzel, Norbert W.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839716/
https://ncbi.nlm.nih.gov/pubmed/33091209
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013480
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