An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair

The geminal frustrated Lewis pair (F(5)C(2))(3)SnCH(2)P(tBu)(2) (1) reacted with N‐sulfinylaniline PhNSO to afford the first sulfur monoxide adduct of a main group metal, (F(5)C(2))(3)SnCH(2)P(tBu)(2)⋅SO (2), which contains a SnCPSO ring. The second product is a phenylnitrene adduct of 1. The surpri...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Holtkamp, Philipp, Glodde, Timo, Poier, Dario, Neumann, Beate, Stammler, Hans‐Georg, Mitzel, Norbert W.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540458/
https://ncbi.nlm.nih.gov/pubmed/32558235
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007653
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