A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis‐Pair and Reductive Elimination

The reactivity of the frustrated Lewis pair (FLP) (F(5)C(2))(3)SnCH(2)P(tBu)(2) (1) was investigated with respect to the activation of elemental hydrogen. The reaction of 1 at elevated hydrogen pressure afforded the intramolecular phosphonium stannate(II) (F(5)C(2))(2)SnCH(2)PH(tBu)(2) (3). It was c...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Holtkamp, Philipp, Schwabedissen, Jan, Neumann, Beate, Stammler, Hans‐Georg, Koptyug, Igor V., Zhivonitko, Vladimir V., Mitzel, Norbert W.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839681/
https://ncbi.nlm.nih.gov/pubmed/33016507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004425
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