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An Experimental Acidity Scale for Intramolecularly Stabilized Silyl Lewis Acids
A new NMR‐based Lewis acidity scale is suggested and its application is demonstrated for a family of silyl Lewis acids. The reaction of p‐fluorobenzonitrile (FBN) with silyl cations that are internally stabilized by interaction with a remote chalcogenyl or halogen donor yields silylated nitrilium io...
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| Veröffentlicht in: | Chemistry |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6899571/ https://ncbi.nlm.nih.gov/pubmed/31469201 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903241 |
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