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Intramolecular Halo Stabilization of Silyl Cations—Silylated Halonium‐ and Bis‐Halo‐Substituted Siliconium Borates
The stabilizing neighboring effect of halo substituents on silyl cations was tested for a series of peri‐halo substituted acenaphthyl‐based silyl cations 3. The chloro‐ (3 b), bromo‐ (3 c), and iodo‐ (3 d) stabilized cations were synthesized by the Corey protocol. Structural and NMR spectroscopic in...
Shranjeno v:
| izdano v: | Chemistry |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2021
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898513/ https://ncbi.nlm.nih.gov/pubmed/33184927 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004838 |
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